TDLAS exploits the rotational vibrational absorption features of gases for laser-based trace gas detection. Sometimes, it is referred to as TDLS, TLS, TLAS or (with a reference) even as TDLARS.
TDLAS is a very strong tool for highly selective and sensitive measurements. It enables:
TDLAS is one of the most sensitive, selective and robust technologies for trace gas monitoring. It is based on the Lambert-Beer law which states a logarithmic relation between the
When a gas has an absorption feature at a specific wavelength, the transmitted intensity declines exponentially with:
I(ν,t) = I0(ν) e-S(T) g(ν,ν0) n L
With n being the number density of the molecular absorbers, I0(ν) the initial laser intensity and I(ν,t) the intensity detected after the probe with an absorption length L.
The absorption line profile is characterized by the temperature-dependent, spectrally integrated line strength S(T), and the normalized (area=1) shape function g(ν,ν0), which is centered at the wavelength ν0.
(Source: #47 High-speed tunable diode laser absorption spectroscopy for sampling-free in-cylinder water vapor concentration measurements in an optical IC engine;
O. Witzel, A. Klein, S. Wagner, C. Meffert, C. Schulz, V. Ebert, Appl. Phys. B, 109, 3, Nov. 2012, pp. 521-532.)
Compared to other highly sensitive technologies, such as gas chromatography TDLAS instruments show
TDLAS is carried out in form of e. g.:
A standard TDLAS setup consists of:
Selecting a suitable absorption line for the TDLAS application is the principal challenge before designing the measurement setup. The outcome of the measurements is highly influenced by the strength of the absorption line as well as by interferences from other gases and the setup itself.
In our Applications by Gas section, we present the most commonly used target wavelengths for major industrial gases.
Child mortality is high among preterm newborn infants. They are often affected by free gas in lungs and intestines, which may lead to the breakdown of vital organs. The current diagnosis is based on X-ray radiography. According to a study a bed-side, rapid, non-intrusive, and gas-specific technique for in vivo gas sensing would improve diagnosis and enhance the babies' chance of survival. The detection method is based on laser spectroscopy
[ 51 ]Ammonium is used as a biomarker for helicobacter pylori infections. These infections are responsible for stomach ulcers. Breath analysis diagnoses the disease in a non-invasive way sparing patients a disagreeable gastroscopy.
[ 63 ]Early fire detection technologies rely on highly sensitive detection of carbon monoxide. Coal-fired power plants, steel mills or biomass deposits use these smoke detectors to increase process and workers safety.
Environmental policies have been implemented worldwide to reduce greenhouse gas emissions. According to the United States Environmental Protection Agency, human activities account for more than three quarters of CO2 emissions. They are mainly due to the combustion of fossil fuels for energy generation, transportation and industry. Remote sensing technologies have been introduced to quantify CO2 and CO emissions in atmosphere.
[ 178 , 115 , 105 , 93 ]H2S occurs as a corrosive, toxic and explosive side product in the petrochemical industry. Continuous monitoring of this hazardous compound is critical to avoid corrosion of natural gas pipelines and ensure workers safety. Real-time analysis is essential to guarantee that burning fuels are H2S clean in order to prevent acid rains.
[ 76 , 69 , 3 ]CO2 is a natural diluent in oil and gas deposits. When it reacts with H2S and H2O steel pipelines corrode. Real-time monitoring of CO2 at natural gas custody transfer points is necessary to avoid contaminated gas from flowing downstream. Immediate measures may be taken to purify the natural gas.
[ 115 ]Water vapour measurement is critical for gas companies to meet quality specifications and to protect pipelines from corrosion. False positives are very costly. Often the gas cannot be delivered if it is "wet".
Continuous monitoring of contents like CO2 or CH4 concentrations is essential for the efficiency of high-temperature processes in e. g. incinerators, furnaces or petrochemical refineries. Managing the CO2 content in combustion processes simultaneously reduces greenhouse gas emissions. This is also relevant for energy generating industries like coal burning power plants.
[ 154 , 124 , 121 , 115 , 112 , 111 , 96 , 94 , 62 , 45 , 40 , 35 , 12 ]The high-resolution transmission molecular absorption database from the Harvard-Smithsonian Center for Astrophysics provides an excellent compilation of spectroscopic parameters.
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